中文名称：二(三氟乙酸)碘苯,≥98%

　　中文别名：[双(三氟乙酰氧基)碘]苯，二(三氟乙酰氧)碘苯

　　英文名称：[Bis(trifluoroacetoxy)iodo]benzene

　　英文别名：Iodosobenzene bis(trifluoroacetate),PIFA

　　分子式：C6H5I(O2CCH3)2

　　纯度：≥98%

　　CAS号：2712-78-9

　　分子式：C10H 5F6IO4

　　分子量：430.04

EINECS登录号：220-308-0

结构式：

外观：白色至类白色结晶性粉末

熔点:121-126°C  

纯度:≥98%

干燥失重:≤0.5%

常温下密封避光保存

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邮编: 201512

最新的应用：

A new and convenient one-pot catalytic addition-elimination reaction converted a range of (E)-3-butenoic acids into the corresponding butenolides in good yields in the presence of 5 mol % diphenyl diselenide and [bis(trifluoroacetoxy)iodo]benzene in acetonitrile.
D. M. Browne, O. Niyomura, T. Wirth, Org. Lett., 2007, 9, 3169-3171.

A mild, oxidative cycloisomerization of cis-enynols using a combination of a hypervalent iodine(III) reagent, molecular iodine, and a base offers an efficient synthesis of 2-acyl furans with diverse substitution patterns in a regioselective manner. A mechanistic proposal for these transformations involving alkyne activation by trifluoroacetylhypoiodite generated in situ is presented.
X. Du, H. Chen, Y. Chen, J. Chen, Y. Liu, Synlett, 2011, 1010-1014.

Various N-arylated and N-alkylated indoles and pyrrole-fused aromatic compounds were synthesized by a phenyliodine bis(trifluoroacetate) (PIFA)-mediated intramolecular cyclization.
Y. Du, R. Liu, G. Linn, K. Zhao, Org. Lett., 2006, 8, 5919-5922.

The hypervalent iodine reagent PIFA promotes the efficient intramolecular electrophilic cyclization of easily accessible alkynylamides and alkynyl carboxylic acids, leading to pyrrolidinone and lactone skeletons, respectively. A synthetic study and a mechanistic proposal for these transformations are presented.
I. Tellitu, S. Serna, m. T. Herrero, I. Moreno, E. Domínguez, R. SanMartin, J. Org. Chem., 2007, 72, 1526-1529.

Oxidative deprotection of several dithiane-containing alkaloids in the presence of bis(trifluoroacetoxy)iodobenzene and a nonchromatic purification cleanly generates the corresponding ketoamines. The described procedure is ideal for labile alkaloids.
F. F. Fleming, L. Funk, R. Altundas, Y. Tu, J. Org. Chem., 2001, 66, 6502 - 6504.