中文名称：二乙酸碘苯,≥99%

　　中文别名：碘苯二乙酸，二乙酰氧基碘苯，二乙酸亚碘酰苯醋酸碘苯

　　英文名称：Iodobenzene diacetate

　　英文别名：Iodosobenzene diacetate

　　分子式：C6H5I(O2CCH3)2

　　纯度：≥99%

　　CAS号：3240-34-4

　　分子式：C10H11IO4

　　分子量：322.10

EINECS登录号：221-808-1

结构式：

外观：白色至类白色结晶性粉末

熔点:159 -165°C  

纯度:≥99%

干燥失重:≤0.5%

常温下密封避光保存

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邮编: 201512

最新的应用：

LiBr is an efficient catalyst for the dihydroxylation of alkenes to afford either syn or anti diols with excellent diastereoselectivity depending upon the use of NaIO₄ or PhI(OAc)₂ as the oxidants.
L. Emmanuvel, T. M. A. Shaikh, A. Sudalai, Org. Lett., 2005, 7, 5071-5074.

Selective syn and anti diacetoxylations of alkenes have been achieved using a PhI(OAc)₂/BF₃·OEt₂ system in the presence and absence of water, respectively. A broad range of substrates including electron-deficient alkenes furnishes the desired products in good to excellent yields and diastereoselectivity. This novel methodology provides an alternative approach for the preparation of various 1,2-diols.
W. Zhong, J. Yang, X. Meng, Z. Li, J. Org. Chem., 2011, 76, 9997-10004.

A one-pot two-step sequence involving an oxidation/imine-iminium formation/reduction allowed the N-alkylation of amines by alcohols. Optically active alcohols and amines can be converted without any epimerization.
C. Guérin, V. Bellosta, G. Guillamot, J. Cossy, Org. Lett., 2011, 13, 3478-3481.

A catalytic Mitsunobu reaction system is described in which the azo reagent is used as an organocatalyst and iodosobenzene diacetate is used as the stoichiometric oxidant. Yields obtained in the catalytic reactions of carboxylic acids and alcohols were slightly lower than those obtained from corresponding stoichiometric reactions.
T. Y. S. But, P. H. Toy, J. Am. Chem. Soc., 2006, 128, 9636-9637.

Phenyliodonium ylides provide easy access to various 1,1-cyclopropane diesters using rhodium or copper catalysis and are safer and convenient alternatives to the corresponding diazo compounds. Moreover, the iodonium ylide of dimethyl malonate was obtained in 78% yield using improved conditions that involve a simple filtration step to isolate the desired product.
S. R. Goudreau, D. Marcoux, A. B. Charette, J. Org. Chem., 2009, 74, 470-473.