加载中…多官能团环氧树脂 multifunctional epoxy resin
(2017-06-05 15:03:05)
标签：
多官能环氧 |
分类： 精译求精及分享 |
缩水甘油胺类
普通AG-80（Araldite SUMI-EPOXY ELM-434，jER
604 ，SE-320)
CAS#31305-94-9
N,N,N',N'-Tetraglycidyl-4,4'-methylenebisbenzenamine(TGDDM)
4,4'-
二氨基二苯甲烷环氧树脂
http://s12/mw690/0025RKpMzy7bDf0H5vtbb&690multifunctional epoxy resin" TITLE="多官能团环氧树脂 multifunctional epoxy resin" />
Viscosity
@ 50°C (122°F), cP :8,000-18,000, mPas
EEW: 117-134 g/Eq
高纯AG-80（Araldite
Viscosity
@ 50°C (cP), (mPas) 3,000 - 6,000
EEW: 109-116 g/Eq
普通AFG-90（Araldite MY 0500，jER
630，SE-300）, CAS#5026-74-4
Triglycidylether of para-aminophenol (TGPAP)
三缩水甘油基对氨基苯酚
http://s11/mw690/0025RKpMzy7bDf0GX34ba&690multifunctional epoxy resin" TITLE="多官能团环氧树脂 multifunctional epoxy resin" />
Viscosity at 25°C: 2 000 – 5 000 mPa.s
EEW: 100 – 115 g/Eq
高纯AFG-90（Araldite MY 0510，jER
630LSD，SE-300P，EPIKOTE Resin 498）
Viscosity at 25°C: 550 – 850 mPa.s
EEW: 96 – 106 g/Eq
Araldite MY 0600, CAS#71604-74-5
Triglycidylether of meta-aminophenol (TGMAP)
三缩水甘油基间氨基苯酚
http://s5/mw690/0025RKpMzy7bDf0O1iA54&690multifunctional epoxy resin" TITLE="多官能团环氧树脂 multifunctional epoxy resin" />
Viscosity at 25°C: 7 000 – 13 000 mPa.s
EEW: 91 – 98 g/Eq
Tg(DMA): 225-240°C(with DDS, Cure
schedule 3 h @ 120°C + 1 h @ 160°C + 2 h @ 180°C)
Araldite MY 0610（EPIKOTE Resin 400）, Distilled
TGMAP
Viscosity
at 25°C: 1 500 – 4 800 mPa.s
EEW: 94 –
102 g/Eq
EPALLOY
GA-240（TETRAD X），CAS#63738-22-7
环氧化间苯二甲胺
http://s8/mw690/0025RKpMzy7bDf0HkBV87&690multifunctional epoxy resin" TITLE="多官能团环氧树脂 multifunctional epoxy resin" />
Viscosity
at 25°C, cps 1,600 - 3,000
EEW: g/eq
95 - 110
TETRAD
C，CAS#65992-66-7
1,3-双(N,N-二缩水甘油氨甲基)环己烷
http://s10/mw690/0025RKpMzy7bDf0SpaVb9&690multifunctional epoxy resin" TITLE="多官能团环氧树脂 multifunctional epoxy resin" />
Viscosity
at 25°C, cps 1,600 - 3,000
EEW: g/eq
95 - 110
其他类型
Tactix
742（ARTF-34，Atul），CAS#66072-38-6
triglycidyl ether of tris (hydroxyphenyl) methane
http://s2/mw690/0025RKpMzy7bDf0Rkl321&690multifunctional epoxy resin" TITLE="多官能团环氧树脂 multifunctional epoxy resin" />
Softening
point：45 - 55 [°C]
Viscosity
at 79 °C (ISO 9371B) :2860[mPa s]
EEW
: 150-170[g/eq]
Tg~299°C(with DDS), DSC
Tg~254°C (with Nadic Methyl Anhydride)
Tg~218°C(with MHHPA)
EPALLOY
9000，CAS#87093-13-8
1, 1, 1-tris-(p-Hydroxyphenyl) Ethane Glycidyl Ether
http://s3/mw690/0025RKpMzy7bDf0H6Uic2&690multifunctional epoxy resin" TITLE="多官能团环氧树脂 multifunctional epoxy resin" />
Viscosity
@ 72°C, cps 5,500 - 6,500
EEW, g/eq
160 - 180
Tg~282°C
(with Nadic Methyl Anhydride)
Tg~220°C
(with MHHPA)
Epon
1031，XB 4399-3，CAS#7328-97-4
tetraglycidyl ether of tetrakis (4-hydroxyphenyl) ethane
http://s1/small/0025RKpMzy7cWNRjbeoc0&690multifunctional epoxy resin" TITLE="多官能团环氧树脂 multifunctional epoxy resin" />
Melt Viscosity @ 150°C：15 dPa·s
EEW, g/eq
195 - 230
Tg~239°C (with Nadic Methyl Anhydride)
Tg~227°C (with MHHPA)
二萘型环氧树脂
1,6–naphthalene diepoxy，CAS#27610-48-6
Araldite MY 0816，EPICLON HP-4032
http://s12/mw690/0025RKpMzy7bDf0Oax5fb&690multifunctional epoxy resin" TITLE="多官能团环氧树脂 multifunctional epoxy resin" />
Viscosity
at 25°C: 25 000 – 80 000 mPa.s
Viscosity
at 50°C: 1500 – 2500 mPa.s
EEW：133 –
154 g/eq
Tg(DMA)~223°C (with 4,4'-DDS, 2h at 150°C + 4h at 180°C + 2h at
200°C)
Tactix 556（Taxtix 756，EPICLON
HP-7200）
dicyclopentadiene-phenol
glycidylether resin
http://s10/bmiddle/0025RKpMzy7cWuKfYfvd9&690multifunctional epoxy resin" TITLE="多官能团环氧树脂 multifunctional epoxy resin" />
Softening
point: 53 [°C]
Viscosity
at 79 °C (ISO 9371B): 2250 [mPa s]
EEW: 215 -
235 [g/eq]
Tg(DMA):234°C (4,4'-DDS，Cure schedule 1h/177°C +2h/232°C）
TECHMORE VG3101,Mitsui
Chemicals
EEW：210 g/eq
Softening point: 61 [°C]
HDT~192℃, with DICY
HDT~212℃, with NMA
HDT~272℃, with DDM
cure schedule
120℃x2hr+160℃x2hr+190℃x4hr
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根据公开资料整理，大部份是比较常见的，以后有空再整理下更特殊的，有兴趣多交流。这些树脂虽然耐温性都很高，但刚性很大，黏度也比较大，所以在实际使用时，往往必须外加增韧剂，而增韧剂的黏度往往更高，PES类更是固体，操作工艺性比较差，所以如果要用它来做耐高温的真空灌注，RTM系统，低粘度、高韧性、高Tg往往很难兼顾，所以如果只使用这些树脂，是很难满足要求的，对于其他特殊结构的树脂/固化剂，还需从分子结构设计上下功夫。
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